As we have seen in the previous section, liquid crystal phase lies
in between the solid and the
liquid phase. Are there any other subphases in the liquid crystal region ?
It turns out that, depending on their amount of order
(which can for example be imposed with external constraints)
liquid crystals show several different subphases.
NEMATIC PHASE
This phase is characterized by the fact that the molecules
try to align themseleves
along the same director but there is not evidence of any positional
order among them. The molecular orientation can be modulated
applying external Electric fields to the material.
The nematic phase is one of the most used in technological applications. LCD
(Liquid Crystals Displays) are a great example of it. A special class of
Nematic liquid-crystals goes under the name of Chiral Nematic. The name is
due to the ability of the molecules to selectively reflect polarized light
(see LCD section for more details).
SMECTIC PHASE
This phase is peculiar of liquid crystals at lower temperature. The main
characteristic of it is that other
then align themselves in a particular direction they also lie in layers.
The motion of the molecules is contrained within these
layers which can slide over
one other like soup.
In this phase is present
some kind of positional order. Depending on the orientation of the molecules
over these planes we can classify different classes
of smectic phases. For instance smectic
of class A have the director perpendicular to the smectic plane.

Smectic phase (Class A)
In the class C the
situation is similar to the one in the previous case but the director forms
a constant angle respect to the normal to
the smectic plane.

Smectic phase (Class C)
As in the nematic case the smectic
of class C have a substate in which they show a chiral phase.
The angle in this case
will rotate from plane to plane forming an
helicoidal path.